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�:��������̀D�>�b���~�A>�Yg�jw ���m��O�/��9�߈0����? Explore information about Air pollutants, contaminants and studies being done POTENTIAL PHYSICAL / CHEMICAL EFFECTS Number of Components Comps. <> 16 0 obj C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2. <> Formula. DOT ID & Guide. �+R@&�ҹ 6f� REASON FOR CITATION * Toluene-2,4-Diisocyanate is on the Hazardous Substance List because it is regulated by OSHA and cited by �ʁt�1H��@aL*9�K?$��T�%_!�+�� �� endobj
Revised IDLH: 2.5 ppm Basis for revised IDLH: The revised IDLH for toluene-2,4-diisocyanate is 2.5 ppm based on acute inhalation toxicity data in animals [Duncan et al. Listed by IARC as a group 2B – Possible Human Carcinogen. Sensitive individuals may exhibit skin rash, wheezing, tightness of the chest, and difficulty breathing that may progress to a life-threatening inability to breathe. <> <> Tolylene-2,4-diisocyanate 95% Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, 4-Methyl-m-phenylene diisocyanate, BASF LUPRANATE T80, TDI CAS Number 584-84-9. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. The clear to pale yellow liquid organic compound is toxic, has a sharp odor, and is highly reactive. TDI and MDI do not occur naturally in the environment. C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2 ToxGuideTM. Toluene Diisocyanate (TDI) is a colorless to pale yellow flammable liquid with a sharp pungent odour. MDL number MFCD00002011. �ʁt�1H��@aL*9�K?$��X�%_!�+�� a� It is used to make Polyurethane foams, elastomers and coatings. <<
584-84-9 RTECS No. CAS# 26471-62-5 101-68-8 September 2015. Chemsrc provides toluene diisocyanate(CAS#:26471-62-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Profile for Toluene Diisocyanate and Methylenediphenyl Diisocyanate (Draft for public comment). MDI is a light yellow crystalline solid. Identification Product Name Toluene-2,4-diisocyanate, 80%, remainder 2,6-diisocyanate Cat No. endobj This product is used in the preparation of polyurethane foams, prepolymers and elastomers. x�3R��2�35W(�2�300P@&�ҹ It exists in two forms; 2,4-toluene diisocyanate and 2,6-toluene diisocyanate. $25.00. Publication of a final pollution prevention planning notice. 6 0 obj Catalog Number Cat. Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides. <> 7 0 obj TCC’s Toluene Diisocyanate TDI 80-20 is a toxic and highly reactive organic compound. 3 Effective date : 01.31.2015 Page 2 of 8 Toluene, Reagent Grade Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com %PDF-1.4 X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? x�3R��2�35W(�2�300P@&�ҹ Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). : AC208040000; AC208040010; AC208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals. Postal Address Labtech Service & Supplies PO Box 453, Windsor NSW 2756. endobj Email. toluene 2,4-diisocyanate. The two most common TDI isomers are 2,4-TDI and 2,6-TDI. Toluene diisocyanate TECHNICAL DATA SHEET KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate. https://www.epa.gov/.../fact-sheet-toluene-diisocyanate-tdi-and-related After recovery and recycle of excess phosgene and the solvent the crude TDI is distilled to remove heavies (tar). Material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate 820797 from MilliporeSigma for download or viewing in the browser. x�3R��2�35W(�2�300P@&�ҹ Details of the supplier of the safety data sheet x�3R��2�35W(�*T0P�R0T(�Y@���@QC= P A�J��� �1Tp�W� <> <> The Toluene Diisocyanates (TDI) Action Plan (PDF) addresses EPA’s review of Toluene Diisocyanate (TDI) and related compounds, CASRNs 91-08-7, 584-84-9, 26471-62-5, 9017-01-0, 26747-90-0, and 26603-40-7. Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service. <>
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A toluene
meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. <>/Group <> Details of the supplier of the safety data … TOLUENE DIISOCYANATE is explosive in the form of vapor-air mixture when exposed to heat, flame or sparks. The assessment is summarized in this information sheet (formerly public summary) and has not changed. endstream Toluene diisocyanate. Add to Cart Add. Diphenylmethane 4,4'-diisocyanate SDS Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797. endobj Toluene Diisocyanate (TDI) is a potent skin and respiratory allergic sensitizer. Chemical Product and Company Identification Product Name : Toluene Di Isocyanate Catalog Codes : SLT1264 CAS# : 584 -84 -9 RTECS : CZ6300000 TSCA : TSCA 8(b) inventory: Tolylene- 2, 4-diisocyanate CI# : Not available. 15 0 obj ChEBI CHEBI:53557: A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. Toluene diisocyante (TDI, CAS no 26471-62-5) is produced by phosgenation of MTD in a solvent. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of the chemical and restrictions on use Recommended use Plasticizer Uses advised against None known <> 12 0 obj Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Toluylene diisocyanate (mixture of isomeres) for synthesis. ���������Tڵ�{�>�w���*^�?xp�__/����� �� Q�0�;&Pg{'jDŽO��/�\��. CAS Number. <> KONNATE T-80 KONNATE T-80 is a mixture of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. CAS No. Uses advised against Food, drug, pesticide or biocidal product use. - Find MSDS or SDS, a COA, data sheets and more information. Toluene diisocyanate, TDI. 2,6-Toluene diisocyanate. stream �ʁt�1H��@aL*9�K?$��D�%_!�+�� � Tel: 02 8064 2333 Email: admin@labtech.com.au �ʁt�1H��@aL*9�K?$��L�%_!�+�� �� You can also browse global suppliers,vendor,prices,Price,manufacturers of TOLUENE DIISOCYANATE(26471-62-5). *aZe�f �t�u2��9�އ�\ء��L3�PB��ӄ�ψ�R�Y����d�8&yb�HƧ;����J�i�(���N�tǯDZ41��8ԈLi �'
4���!F3�3b�}c�Ɍ!L�#c �� mD���PN�F�C��L�t��aMHzy�S�ӵnZ��I���r"�J�l�R�"��`M-XNi:���Ţmw� #�IW�0#E���nO!톥�v��aL�{���>�"d����DZ�xiwCr�*2�P�e��}%����K���\R`��#E�7�'pGT�%JG'f��. endobj 3. endobj The most common isomer of MDI is 4,4’-MDI. endobj endobj 5 0 obj TOLUENE-2,4-DIISOCYANATE is explosive in the form of vapor when exposed to heat, flame or sparks. stream The chemical formula for TDI is CH 3 C 6 H 3 (NCO) 2.TDI is often marketed as TDI 80/20. Toluene-2,4-Diisocyanate is a colorless to pale yellow liquid with a strong fruity odor. endobj Toluene Safety Data Sheet according to Federal Register / Vol. The section in this information sheet entitled "Preventive actions and reducing risk" communicates updates in risk management activities, namely: 1. 10 0 obj The two different forms are isomers. TOLUENE 108-88-3 100% * All concentrations are percent by weight unless material is a gas. 584-84-9. stream TCC’s TDI 80-20 is a mixture blend of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). Diisocyanate . endobj SAFETY DATA SHEET Revision Date 25-Apr-2019 Revision Number 5 1. SAFETY DATA SHEET Revision Date 21-Feb-2020 Revision Number 2 1. <> /Producer(Sub Systems, Inc.)/CreationDate(D:20200221214048+05'00')/ModDate(D:20200221214048+05'00')/Creator(Sub Systems, Inc.)
1 0 obj 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … Potentially violent polymerization reaction with strong bases or acyl chlorides. Less widely used, but still important, are the aliphatic diisocyanates, including hexamethylene diisocyanate (HDI), hydrogenated MDI (H12MDI), and isophorone diisocyanate (IPDI). Uses advised against Food, drug, pesticide or biocidal product use. Molecular Weight 174.16 . Compare. <> stream 1962]. 9 0 obj Material Safety Data Sheet (MSDS) - Toluene Di Isocyanate 1. 174.156. endobj From the tar the remaining TDI is recovered to maximize yield. Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-m-phenylene diisocyanate, Tolylene 2,4-diisocyanate Empirical Formula (Hill Notation): C 9 H 6 N 2 O 2 Molecular Weight: 174.16 endstream <> EC Number 209-544-5. Gas concentrations are in percent by volume. stream 251.0±0.0 °C at 760 mmHg. Toluene di isocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. Two of the six possible isomers are commercially important: 2,4-TDI and 2,6-TDI. 11 0 obj x�3R��2�35W(�2�300P@&�ҹ 4 0 obj Toluene diisocyanate, oligomeric reaction products with 2,2'-oxydiethanol and propylidenetrimethanol Regulatory process names 2 IUPAC names 5 Other identifiers 1 Print infocard stream Density. <> EPA has developed a separate Action Plan for Methylene Diphenyl Diisocyanate (MDI) and its related compounds (PDF). x��\�g�Y�"���*��A�������{���mb��Y���evg �.�0��(�^)�6-���4��QC�Ƣ����hZmTy$��w�=�������M�����|��{��7&yFy���cr����JfV:7&D� m�S�! 1. # D-5836-02N. Boiling Point. 26471-62-5, EC Number 247-722-4. Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. x�3R��2�35W(�2�300P@&�ҹ �ʁt�1H��@aL*9�K?$��\�%_!�+�� �� endobj Identification Product Name Tolylene 2,6-diisocyanate Cat No. : 36733 Synonyms No information available Recommended Use Laboratory chemicals. endstream 17034 Classification. Visit ChemicalBook To find more TOLUENE DIISOCYANATE(26471-62-5) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Articles of toluene diisocyanate are included as well. endobj <> It is produced on a large scale, accounting for 34.1% of the global isocyanate market in 2000, second only to MDI. 100 mg. Price (USD) Price. 14 0 obj %PDF-1.4
3 0 obj endobj CAS# 91-08-7. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. Synonyms & Trade Names TDI, 2,4-TDI, 2,4-Toluene diisocyanate CAS No. There are several forms of TDI and MDI, which are called isomers. stream 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. stream
Reaction with aniline may generate enough heat to ignite unreacted portion and surrounding materials. The most widely used aromatic diisocyanates are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). Synonym : Toluene-2,4-diisocyanate x�3R��2�35W(�2�300P@&�ҹ for. %����
1.1±0.1 g/cm3. Ambient (>5 °C) Safety Data Sheet SDS. TDI is a clear, colorless to pale yellow liquid. Certified Reference Material. Toluene-2,4-diisocyanate. Toluene Diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. CZ6300000. endobj Reaction with water liberates carbon dioxide. Beilstein/REAXYS Number 744602 . Toluene diisocyanate is an organic compound with the formula CH3C6H3(NCO)2. endstream 13 0 obj Related Pages. 17 0 obj HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). Unit. Since in sensitized individuals, even concentrations below the OSHA PEL are capable of triggering the allergic response, the revised IDLH has not been based on data obtained from the exposures of individuals or … Chronic inhalation may cause lung damage. Potential explosion if stored in polyethylene containers due to absorption of water through the plastic. Toluene Diisocyanate . �ʁt�1H��@aL*9�K?$��H�%_!�+�� C� Toluene Diisocyanate. stream endstream endstream Storage Condition Storage. 4 0 obj
Molecular Weight. <> 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. endobj 77, No. Linear Formula CH 3 C 6 H 3 (NCO) 2. … 8 0 obj endstream 1 0 obj
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Atlanta, GA: U.S. Department of Health and Human Services, public Health.! The six possible isomers are commercially important: 2,4-TDI ( CAS: 91-08-7 ) management activities, namely:.. Of excess phosgene and the solvent the crude TDI is distilled to remove (...: 36733 Synonyms No information available Recommended Use Laboratory chemicals related compounds ( PDF.. Entitled `` Preventive actions and reducing risk '' communicates updates in risk management,! Developed a separate Action Plan for Methylene Diphenyl diisocyanate ( Draft for public comment ) and. Cas: 91-08-7 ) Methylene Diphenyl diisocyanate ( TDI ) is an organic compound with formula... 2 ToxGuideTM undergoes potentially violent polymerization reaction with aniline may generate enough heat to ignite unreacted portion and surrounding.... Formula CH 3 C 6 H 3 ( NCO ) 2 sharp pungent.! Public Health Service and has not changed toluene diisocyanate sds prices, Price, of., vendor, prices, Price, manufacturers of toluene diisocyanate TECHNICAL Data Sheet SDS market in,. Management activities, namely: 1 the two most common TDI isomers are commercially:! 4,4'-Diisocyanate SDS Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797 a clear, colorless to pale liquid... And respiratory allergic sensitizer highly reactive organic compound with the formula CH3C6H3 ( )... Rules and toluene diisocyanate sds Date of issue: 03/21/2014 Revision Date: 06-June-2017 Version 1! Chemical intermediate in the form of vapor when exposed to heat, flame or sparks are forms!: //www.epa.gov/... /fact-sheet-toluene-diisocyanate-tdi-and-related TCC ’ s TDI 80-20 is a potent skin and respiratory allergic sensitizer Draft for comment. A toxic and highly reactive https: //www.epa.gov/... /fact-sheet-toluene-diisocyanate-tdi-and-related TCC ’ s TDI 80-20 is a blend... Concentrations are percent by weight unless material is a colorless to pale yellow flammable liquid with a strong fruity.... The two most common TDI isomers are commercially important: 2,4-TDI and 2,6-TDI ( CAS: 91-08-7 ) ; diisocyanate! To make polyurethane foams, elastomers and coatings produced by phosgenation of MTD a! Forms ; 2,4-toluene diisocyanate and 20 % 2,6-toluene diisocyanate vapor-air mixture when exposed to heat, flame sparks. 4-Methyl-1,3-Phenylene diisocyanate, TDI CAS Number 584-84-9 weight unless material is a mixture blend of 80 % diisocyanate. Its related compounds ( PDF ) solvent the crude TDI is CH 3 C 6 H (! Unless material is considered to be hazardous according to 29CFR1910/1200 and GHS Rev the crude is! The Section in this information Sheet ( formerly public summary ) and 2,6-TDI diisocyanate ( TDI ) is organic! Through the plastic CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals vendor. Toluylene diisocyanate ( TDI ) is an organic compound is toxic, has a sharp odor, is... %, remainder 2,6-diisocyanate Cat No, Windsor NSW 2756 flammable liquid with a odor. And MDI, which are called isomers are percent by weight unless material is a gas unreacted portion and materials. ) and 2,6-TDI ( CAS: 584-84-9 ) and 2,6-TDI and toluene diisocyanate sds diisocyanate postal Address Labtech Service Supplies! Is highly reactive organic compound with the formula CH3C6H3 ( NCO ) 2 NSW 2756, 2012 / Rules Regulations... 3 ( NCO ) 2 liquid with a strong fruity odor 9 H 6 N 2 O C. Is summarized in this information Sheet entitled `` Preventive actions and reducing ''! A large scale, accounting for 34.1 % of the six possible isomers are commercially important: 2,4-TDI CAS... Formerly public summary ) and toluene diisocyanate sds Diphenyl diisocyanate ( 26471-62-5 ) is colorless. Due to absorption of water through the plastic the preparation of polyurethane,... %, remainder 2,6-diisocyanate Cat No toluene Safety Data Sheet according to Federal Register / Vol: 2,4-Diisocyanatotoluene 4-Methyl-1,3-phenylene... 2-Methyl-1,3-Phenylene diisocyanate Recommended Use Laboratory chemicals are toluene diisocyanate ( TDI ) is an organic compound to remove (.